MicroActive 2.0 and MicroActive for 3Flex include a powerful utility for including the pore size distribution from mercury porosimetry analyses with pore size distributions calculated from gas adsorption isotherms. This new import function allows users to rapidly view micro, meso, and macro pore size distributions in one easy to use application.
This new import function has been added that allows users to rapidly include pore size distributions from other devices to be included into the standard Micromeritics sample file (SMP file). The pore size data from the external source such as a mercury porosimeter is imported from a simple text file. The first line of the text file includes a description, size units, quantity units, and type of data with the following format.
<description> (<pore width units>, <quantity units>, <type>)
The porosimetry data then follows with the pore width in the first column and the quantity in the second column. An example of the format is given in figure 1. The intrusion data must be strictly increasing and extrusion data must be strictly decreasing.
|description||:||used to identify the imported data and as the graph legend|
|pore width units||:||Ångstroms – A, nanometers – nm, or micrometers – um|
|quantity units||:||ml/g or cm3/g|
|type||:||incremental or cumulative|
The incremental or cumulative data is available from the Micromeritics AutoPore 9500 application. The data may be copied by right-clicking on either the cumulative or incremental pore volume graphs generated by the AutoPore reports and then using the Copy as text option. A file to be imported is restricted to either intrusion or extrusion data. However, multiple files may be imported to allow the inclusion of both intrusion and extrusion data.
The pore volume data may be integrated into a sample file (SMP file) using the Import … function located on the Report Options tab in the Advanced view of the SMP file (figure 2).
The Import … button opens a dialog, figure 3 and lists any pore volume data that have been previously imported to the SMP file and each set of pore volume data is listed by description. Additional data be be imported or removed from the SMP using the Select Imported Overlays dialog.
If an error is encountered while importing the mercury porosimetry data, a descriptive message is displayed that includes a description of the correct file format, figure 4.
The imported data may then be used as an overlay with cumulative, differential, or log differential pore size distributions. The overlay is selected by editing the options for the BJH, Dollimore-Heal, Horvath-Kawazoe, and DFT pore size reports. Each report has the option for including an overlay and the Imported Data may be selected as seen in figure 5
Commercial catalysts are commonly analyzed using nitrogen adsorption to determine surface area and porosity. The pore size distribution may then be calculated from the nitrogen adsorption isotherm using BJH. Mercury porosimetry is also commonly employed to determine the pore volume distribution of catalysts and the pore volume distribution may overlaid with the distribution calculated from the nitrogen adsorption isotherm.
In this example, the Micromeritics chemisorption reference material a 0.5 wt% platinum on alumina sample was characterized using nitrogen adsorption and mercury porosimetry. The nitrogen adsorption and desorption isotherms were used to calculate the pore size distribution using the BJH method. Both mercury intrusion and extrusion data were imported into the gas adsorption SMP file (figure 6).
The overlay of the pore size distributions is given if figure 6. Based upon this simple overlay of the log differential pore volume distribution, the size distribution (figure 6 in red) calculated from the desorption branch of the isotherm agrees well with the pores size distribution (in green) determined by mercury intrusion porosimetry.
MicroActive version 2.0 provides new and unique capabilities for integrating pore volume data from mercury intrusion analyses with the pore size distributions calculated from gas adsorption isotherms. The MicroActive software is compatible with SMP files from Micromeritics broad range of gas adsorption instruments and provides a new capability for examining new or historical pore volume distributions.